Optimization parameters and synthesis of fluorine doped tin oxide for dye-sensitized solar cells

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Suyitno, Arifin Zainal, Arif Santoso Ahmad, Tara Setyaji Argatya, Ubaidillah

2014 Applied Mechanics and Materials Vol. 575 Conference paper Cited by 25

Abstract

Transparent conductive oxide (TCO) is one of the important components in dye-sensitized solar cells. The main requirements of TCO for dye-sensitized solar cells are having a low electrical resistance and a high light transmittance. This study focuses on the synthesis of fluorine-doped tin oxide including its optimization. The synthesis of fluorine-doped tin oxide has been conducted under spray pyrolysis technique in which a precursor solution of SnCl2:F having concentration of 0.3, 0.5, 0.7, and 0.9 M. The spray pyrolysis was performed using a nebulizer with deposition time of 10 min. The glass substrate was heated at a temperature of 400, 450, and 500°C prior to deposition. The fluorine doped tin oxide was then measured the electrical resistivity for each area of 1 cm2. Therefore, the mean and distribution of electrical resistivity of fluorine-doped tin oxide with an area of 10 × 10 cm then were predicted. In addition, the morphology and transmittance of fluorine-doped tin oxide are also examined. The optimization of the synthesis process of fluorine-doped tin oxide using spray pyrolysis was obtained at a concentration of 0.7 M with a sintering temperature of 400°C. The best fluorine-doped tin oxide has been also fabricated into the dye-sensitized solar cell and the performance has been studied. © (2014) Trans Tech Publications, Switzerland.

Affiliations

Mechanical Engineering Department, Sebelas Maret University, Surakarta, Jl. Ir. Sutami 36A, Indonesia; Research Group of Applied Energy Conversion and Nanotechnology, Sebelas Maret University, Surakarta, Jl. Ir. Sutami 36 A, Indonesia; Graduate School of Mechanical Engineering, Brawijaya University, Malang, Jl. MT.Haryono 167, Indonesia