The Effect of Substrate Temperature on Surface Modification of Polystyrene by using Nitrogen Plasma

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A.F. Novi, D.J.D.H. Santjojo, Masruroh

2017 IOP Conference Series: Materials Science and Engineering Vol. 202 Issue 1 Conference paper Cited by 2 Quartile

Abstract

Studies on the effect of substrate temperature on the modification process of a thin layer of polystyrene samples deposited on glass by using spin coating technique have been conducted. The polystyrene thin film surface was modified by using nitrogen plasma generated in a vacuum reactor by a capacitive plasma generator with a frequency of 40 kHz. The substrate temperature was set by variation of 60, 70 and 80 °C during the modification process to determine the effect of substrate temperature on the level of roughness and hydrophobicity of the film. Observations were conducted by using optical microscopy, optical micro-profiler, and measuring the contact angle of liquid. The results showed a decrease in roughness due to modification at a temperature of 60 °C and 70 °C. On the other hand, the treatment at a temperature of 80 °C resulted in an increase of roughness. By measuring the contact angle, it was proven that hydrophobicity is not only influenced by the surface roughness of thin layers. © Published under licence by IOP Publishing Ltd.

Affiliations

Jurusan Fisika FMIPA Univ. Brawijaya, Jl. Veteran, Malang, 65145, Indonesia